Self Quiz Answers
1. Name the following:
| a. |
CH3 - CH2 - NH2 |
ethylamine
or
aminoethane |
| b. |
O
||
CH3 - C - NH2 |
acetamide
or
ethanamide |
| c. |
CH3 - CH2 - CH2 - N - CH3
|
H |
methylpropylamine
or
N-methyl-1-aminopropane |
| d. |
O
||
NH2 - C - CH2 - CH3 |
propanamide |
| e. |
 |
aminobenzene
or
aniline |
| f. |
CH3 - N - CH2 - CH2
- CH3
|
CH3 |
dimethylpropylamine
or
N,N-dimethyl-1-aminopropane |
| g. |
O
||
H - C - NH2 |
formamide
or
methanamide |
2. Draw structures for the following:
| a. |
N-ethylmethanamide |
![Structure of N-ethylmethanamide. [str5sq2a.jpg]](images/str5sq2a.jpg) |
| b. |
N-ethylformamide |
 |
| c. |
trimethylamine |
![Structure of trimethylamine. [str5sq2c.jpg]](images/str5sq2c.jpg) |
| d. |
3-aminohexane |
![Structure of 3-aminohexane. [str5sq2d.jpg]](images/str5sq2d.jpg) |
| e. |
hexanamide |
![Structure of hexanamide. [str5sq2e.jpg]](images/str5sq2e.jpg) |
| f. |
methylamine |
![Structure of methylamine. [str5sq2f.jpg]](images/str5sq2f.jpg) |
3. Write an equation showing how an amide could be prepared from ammonia and acetic
acid, name the amide, and write an equation showing how the reaction could be reversed.
O
||
CH3 - C - OH |
+ |
NH3 |
intermolecular
®
dehydration |
O
||
CH3 - C - NH2 |
+ |
H2O |
| acetic acid |
|
ammonia |
|
acetamide |
|
|
|
O
||
CH3 - C - NH2 |
+ |
H2O |
hydrolysis
®
|
O
||
CH3 - C - OH |
+ |
NH3 |
|
4. Which of these molecules are capable of forming hydrogen bonds with water? Also,
draw a diagram showing how one of these molecules would form hydrogen bonds with water.
| a. |
![Structure of 1,2-dichlorobenzene. [str5odcb.jpg]](images/str5odcb.jpg) |
no |
|
| b. |
![Structure of aniline. [str5ani3.jpg]](images/str5ani3.jpg) |
yes |
![Structure of aniline with hydrogen bonding. [str5sq4b.jpg]](images/str5sq4b.jpg) |
| c. |
CH3 - NH2
|
yes |
![Structure of methylamine with hydrogen bonding. [str5sq4c.jpg]](images/str5sq4c.jpg) |
| d. |
CH3
|
CH3 - N - CH3 |
yes, but only when water provides the
H |
![Structure of trimethylamine wit hydrogen bonding. [str5sq4d.jpg]](images/str5sq4d.jpg) |
| e. |
O
||
CH3 - C - NH2 |
yes |
![Structure of acetamide with hydrogen bonding. [str5sq4e.jpg]](images/str5sq4e.jpg) |
5. Which of the following contain an asymmetric carbon atom?
| a. |
3-hexanol |
yes |
| b. |
1-propanol |
no |
| c. |
acetaldehyde |
no |
| d. |
CH3 - CH2 - CH - CH3
|
NH2 |
yes |
| e. |
Br
|
Cl - C - I
|
Cl |
no |
| f. |
O
||
C
/ \
H H |
no |
| g. |
CH3 - CH2 - CH - CH2 - Cl
|
CH3 |
yes |
6. Which of the following are heterocyclic compounds?
| a. |
![Structure of naphthalene. [str5naph.jpg]](images/str5naph.jpg) |
no |
| b. |
 |
no |
| c. |
![Structure of compound in question 6c of self quiz. [str5sq6c.jpg]](images/str5sq6c.jpg) |
yes |
| d. |
![Structure of compound in question 6d of self quiz. [str5sq6d.jpg]](images/str5sq6d.jpg) |
yes |
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E-mail instructor:
Sue Egglilng
Clackamas Community College
©2001, 2003 Clackamas Community College, Hal Bender
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