Self Quiz Answers
1. Name the following:
| a. |
O
| | ||
- C - C - O - C - H
| | |
ethyl formate
or
ethyl methanoate |
| b. |
| |
| |
- C - C - O - C - C -
| | | |
-C-
| |
ethyl isopropyl ether |
| c. |
O
| | ||
|
-C - C - C - O - C -
| | | |
methyl propanoate |
| d. |
|
O -C-
|| | |
|
C - C - C - C -
/ | | |
HO
|
3-methylbutanoic acid |
2. Draw structural formulas for the following:
| a. |
formic acid |
O
||
H-O-C-H
|
| b. |
methyl acetate |
O
| || |
-C-C-O-C-
| | |
| c. |
methyl pentyl ether |
| | |
| | |
-C-O-C-C-C-C-C-
| | | | | | |
3. Classify each of the compounds in questions 1 and 2:
| 1-a. |
O
| | ||
- C - C - O - C - H
| | |
ester |
| 1-b. |
| |
| |
- C - C - O - C - C -
| | | |
-C-
| |
ether |
| 1-c. |
O
| | ||
|
-C - C - C - O - C -
| | | |
ester |
| 1-d. |
|
O -C-
|| | |
|
C - C - C - C -
/ | | |
HO
|
carboxylic acid |
| 2-a. |
formic acid
|
carboxylic acid |
| 2-b. |
methyl acetate
|
ester |
| 2-c. |
methyl pentyl ether
|
ether |
4. Identify the following as soaps, phosphate esters, or fats:
| a. |
OH
|
O-P-OCH2CH3
|
O
|
CH3 |
phosphate ester |
| b. |
O
||
C15H32C-ONa |
soap |
| c. |
O
||
H2C-O-C-C11H23
|
| O
| ||
HC-O-C-C11H23
|
| O
| ||
H2C-O-C-C11H23 |
fat |
5. Write an equation showing how:
a. methyl ethyl ether can be prepared from methanol and ethanol.
dehydration
CH3-O-H + H-O-CH2-CH3
¾¾¾¾¾¾¾® CH3-O-CH2-CH3
+ H2O
H2SO4, heat |
b. ethyl formate can be prepared from an acid and an alcohol.
O
||
H-C-OH
|
+ H-O-CH2-CH3
|
dehydration
¾¾¾¾¾¾¾®
H+, heat |
O
||
H-C-O-CH2-CH3
|
+ H2O |
|
c. propanoic acid can be prepared from an alcohol.
| CH3-CH2-CH2-OH |
oxidation
¾¾¾¾¾¾¾¾¾®
K2Cr2O7, H2SO4 |
O
//
CH3-CH2-C
\
OH |
|
d. methyl acetate can be prepared from methanol and ethene.
This involves multiple steps: use ethene (via ethanol) to make
acetic acid, then combine with methanol to make methyl acetate.
| CH2=CH2 |
+ H2O |
addition
¾¾¾¾¾® |
CH3CH2OH |
oxidation
¾¾¾¾¾®
|
CH3COOH |
|
O
||
CH3-C-OH
|
+ H-O-CH3
|
dehydration
¾¾¾¾¾¾¾®
H+, heat |
O
||
CH3-C-O-CH3
|
+ H2O |
|
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E-mail instructor:
Sue Eggling
Clackamas Community College
©2001, 2003 Clackamas Community College, Hal Bender
|