Third Example
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Third Example

Iron and Chlorine

 

Iron is a transition metal. With transition metals you cannot count on knowing the ionic charge just from its position in the periodic table. For most transition metals, you will have to look up what charges actually exist for that element. You can look these up in your textbook or you can look back at the list in your workbook. However, you should have memorized the charges for copper and iron. Iron has an ion with a +2 charge called iron(II) ion or ferrous ion, and one with a +3 charge called iron(III) ion or ferric ion. Chlorine, of course, has a -1 charge.

Because there are two types of cations, two different compounds can be formed. When the Fe2+ combines with chloride, you will get FeCl2. FeCl2 is named iron(II) chloride because it is made of iron(II) ions and chloride ions. It can also be called ferrous chloride.

If the iron +3 ion combines with chloride, then that will give you FeCl3 because three chloride ions are needed to neutralize the charge on a +3 ion. FeCl3 is named iron(III) chloride because it is made of iron(III) ions and chloride ions. It can also be called ferric chloride.

Ions

Fe2+

Cl-

Fe3+

Charge ratios

2

1

3

1
Ion ratios
1
2
1
3
Formulas FeCl2 FeCl3
Names iron(II) chloride iron(III) chloride

Again note that in in these compounds the charge ratios can be reversed to get the atom ratios.

 

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