Iron is a transition metal. With transition metals you cannot count on
knowing the ionic charge just from its position in the periodic table. For most transition
metals, you will have to look up what charges actually exist for that element. You can
look these up in your textbook or you can look back at the list in your workbook. However,
you should have memorized the charges for copper and iron. Iron has an ion with a +2
charge called iron(II) ion or ferrous ion, and one with a +3 charge called iron(III) ion
or ferric ion. Chlorine, of course, has a -1 charge.
Because there are two types of cations, two different compounds can be formed. When the
Fe2+ combines with chloride, you will get FeCl2. FeCl2 is
named iron(II) chloride because it is made of iron(II) ions and chloride ions. It can also
be called ferrous chloride.
If the iron +3 ion combines with chloride, then that will give you FeCl3
because three chloride ions are needed to neutralize the charge on a +3 ion. FeCl3
is named iron(III) chloride because it is made of iron(III) ions and chloride ions. It can
also be called ferric chloride.