Deducing Lewis Diagrams
Home Up Predicting Formulas Limitations of Method Deducing Lewis Diagrams

 

Example: Carbon Monoxide
Example: Ethene
Practice

Deducing Lewis Diagrams

Using molecular formulas to determine Lewis diagrams

There are many molecular compounds for which it is not easy to predict the formula based on the principles we've just been using. Even so, you will sometimes need to draw Lewis diagrams for them. One reason for doing this is to determine molecular shapes and properties. In such cases you will be given the name or molecular formula and be asked to draw the Lewis diagram for it. Sometimes that will be an easy task and the dots will just fall into place. Other times it will not be so easy. Let me give you some guidelines that I use in such cases. Your textbook and other instructors use different approaches. So, if my method doesn't work for you, try one or more of the others.

Here are some guidelines. Pick a central atom, if there is one. Usually it is the one that needs the most bonds. Arrange the electrons of that central atom to meet the needs of the atoms around it. Then arrange the electrons of the surrounding atoms to meets the needs of the central atom. Also, think "covalent means cooperate." The atoms have to cooperate with one another to do covalent bonding.
Guidelines
Pick a central atom (or atoms)
Arrange central atom's electrons
to meet surrounding atoms' needs
Arrange surrounding atoms' electrons
to meet central atom's needs
Think "covalent means cooperate"

 

This approach is somewhat intuitive - presumably, you think like an atom and put your electron dots where they will best accommodate the atoms to which you will be bonding.

Other Approaches

Other, more systematic approaches can also be used. If you have trouble using the previous approach try using the "Systematic Approach" shown in example 18 in your workbook. Your textbook also outlines a method in the section on "Writing Lewis Structures." Or you can get some additional help from an instructor or other students to work out an approach that works best for you.

Examples and Practice

Using the other pages in this section you can work through a couple of examples   using the method I have described. The formulas let you practice using the guidelines, or try using the other options. (These examples are also shown in examples 16,a-b in your workbook, and the practice is in exercises 16,c-e and 17.)

 

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