Döbereiner

Some of the first elemental similarities were noted by a German chemist named Döbereiner in 1829. His observations began with bromine which had just been discovered. He noticed that the properties of bromine were similar to chlorine and iodine. Not only were they similar but various properties of bromine, including the atomic weight, fell midway between the properties of chlorine and iodine. Not only were there similarities in the properties but also there was a pattern or trend within the group of regularly increasing atomic weights.

Döbereiner's Triads

Ca 40.1
Sr 87.6
Ba 137.3
S 32.1
Se 79.0
Te 127.6
Cl 35.5
Br 79.9
I 126.9
He noticed a couple other groups of elements with patterns like this. They were calcium, barium, and strontium; also sulfur, selenium, and tellurium. He described these groups as being triads, groups of three elements that had similar properties. Not much was made of this because the triads only covered one-sixth of the known elements. Most chemists of the time considered them to be inconsequential coincidence.